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Tested Oct 2016 and there must have been some changes in bus schedules because there is no bus from Murcia to Santomera/La Matanza. The farthest you can go by bus is to Santomera. I asked various bus drivers and lady in the ticket office and everywhere the answer was the same - no more buses to Santomera/La Matanza. For us, hitchhikers, it means a longer walk to the petrol station...
So there is just a bus going to Santomera. It takes ~40 min from Murcia central bus station to Santomera and costs 2,05 €. Get out on the last bus stop in Santomera and be prepared for ~3km walk till autovia plus ~1km on autovia itself untill you reach the gas station (there's no other way, you basically have to walk a bit on the autovia in order to get to the spot)...
Despide difficulties to get to the there the petrol station is quite busy and it's fairly easy to catch a long ride there.
(chaichai)